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Bis(bipyridyl)silicon(IV) compounds – synthesis, characterization, and catalytic properties.
Title
Bis(bipyridyl)silicon(IV) compounds – synthesis, characterization, and catalytic properties.
Author
Maguylo, Christina
Date Created
2015
Subjects--Topical
Chemistry, Chemistry, Inorganic
Description
A series of novel hexacoordinate bis-bipyridylsilicon(IV) complexes have been synthesized by reacting [Si(bipy)2I2]I2 with the appropriate alcohol or diol. Characterization was done and crystal structures have been obtained for the complexes: [Si(...
Hexacoordinate Silicon Complexes as Cathodic Colorants
Title
Hexacoordinate Silicon Complexes as Cathodic Colorants
Author
Peloquin, Derek
Date Created
2016
Subjects--Topical
Nanoscience, Chemistry, Chemistry, Inorganic
Description
Electrochemical and spectroelectrochemical characterization of hexacoordinate polypyridine silicon complexes show that they are fitting candidates for electrochromic applications. Tris(bipyridine)silicon(IV), [Si(bpy)3]+4, is colorless in acetonit...
Influence of Functional Groups on the Photodynamic Therapy and Internalization of Porphyrin Modified Polyhedral Oligomeric Silsesquioxane (POSS) Molecules in Mammalian Cells
Title
Influence of Functional Groups on the Photodynamic Therapy and Internalization of Porphyrin Modified Polyhedral Oligomeric Silsesquioxane (POSS) Molecules in Mammalian Cells
Author
Johnston, Alexis
Date Created
2020
Subjects--Topical
Chemistry, Chemistry, Inorganic, Chemistry, Organic
Description
Polyhedral Oligomeric Silsesquioxane (POSS) molecules are highly ordered organic- inorganic hybrid materials with a cage like core of alternating silicon and oxygen atoms surrounded by eight pedant organic residues. These compounds are well-define...
Synthesis and Reactivity of Six-Membered N-Heterocyclic Chalcogenones
Title
Synthesis and Reactivity of Six-Membered N-Heterocyclic Chalcogenones
Author
Flanagan, Jerrod
Date Created
2017
Subjects--Topical
Chemistry, Chemistry, Inorganic
Description
The synthesis and coordination chemistry of N-heterocyclic thione (NHT) and selone (NHSe) ligands containing a saturated pyrimidine ring and bulky aromatic substituents on the nitrogen atoms is described in this thesis. To further understand the e...
TRINUCLEAR METAL CHALCOGENIDE CLUSTERS AS PRECURSORS FOR SUPERATOMIC SOLIDS AND CLUSTER ORGANIC FRAMEWORKS
Title
TRINUCLEAR METAL CHALCOGENIDE CLUSTERS AS PRECURSORS FOR SUPERATOMIC SOLIDS AND CLUSTER ORGANIC FRAMEWORKS
Author
Shott, Jessica
Date Created
2017
Subjects--Topical
Nanoscience, Chemistry, Chemistry, Inorganic
Description
Inorganic molecular clusters Ni3(μ3-I)2(μ2-dppm)3 (1), Ni3(μ3-Te)2(μ2-dppm)3 (2), Ni3(μ3-Se)2(μ2-dppm)3 (3), Ni3(μ3-S)2(μ2-dppm)3 (4), Co4(μ3-S)4(PPri3)4 (5), and Mo3(μ3-S)2(μ2-S)3(PMe3)6 (6) have been used as building block precursors in the form...