Metal sulfide clusters are attractive components for flow batteries owing to the abundance of their constituent atoms and their tunable size, solubility, and redox properties. We prepared an atomically precise cobalt sulfide cluster, Co6S8(PTA)6•4...
The unsubstituted [n]radialenes are a unique class of alicyclic hydrocarbons with radiating alkenes. These compounds are typically difficult to handle and polymerize rapidly. A number of stable radialene derivatives that exhibit reversible electro...
Inorganic molecular clusters Ni3(μ3-I)2(μ2-dppm)3 (1), Ni3(μ3-Te)2(μ2-dppm)3 (2), Ni3(μ3-Se)2(μ2-dppm)3 (3), Ni3(μ3-S)2(μ2-dppm)3 (4), Co4(μ3-S)4(PPri3)4 (5), and Mo3(μ3-S)2(μ2-S)3(PMe3)6 (6) have been used as building block precursors in the form...
