Search results
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Title
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Determining the Rate of Ligand-Induced Charge-Transfer Effects on Quantum Dots
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Author
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Bowman, Cale
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Date Created
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2015
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Subjects--Topical
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Chemistry
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Description
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In this report, charge carrier dynamics and rate of electron transfer is investigated between two bis(thioether)silane (R2BtsMe) ligands and 2.65 nm CdSe core quantum dots (QDs). Isothermal titration calorimetry (ITC) data is used to determine bin...
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Title
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Halogenated Tags for the Investigation of Enzyme Specificity
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Author
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Houde, Hailey
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Date Created
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2023
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Subjects--Topical
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Biochemistry, Chemistry
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Description
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The bacterial enzyme undecaprenyl pyrophosphate synthase (UppS) is present in most prokaryotes and is needed for bacterial survival. UppS produces the essential lipid carrier, bactoprenyl monophosphate (BP). BP is critical for the structural integ...
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Title
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INTERFACE STUDY OF SPIRO-OMETAD ON PASSIVATED P-, N-, AND N+-Si(111) FOR USE IN TANDEM PEROVSKITE/SILICON SOLAR CELL DEVICES
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Author
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Nguyen, Li
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Date Created
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2015
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Subjects--Topical
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Chemistry, Chemistry, Physical and theoretical, Renewable energy sources
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Description
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The organic semiconductor 2,2’,7,7’-tetrakis-(N,N-di-p-methoxyphenylamine)9,9’-spirobifluorene (Spiro-OMeTAD) contact properties are studied on p-, n-, and n+-type silicon. Spiro-OMeTAD is a solid state hole conductor that has notably been used in...
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Title
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Quantum Enhanced Electron Transfer in Coupled Porphyrins
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Author
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Pedersen, Andrew
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Date Created
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2015
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Subjects--Topical
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Chemistry
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Description
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The role of solar power as a renewable energy source is of ever increasing importance to our future. It is inevitable then that the focus of much research would be looking at nature’s solutions to solar power with photosynthesis. A theoretical pap...
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Title
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SYNTHESIS OF THIAZOLOTHIAZOLE FUNCTIONALIZED PORPHYRINS FOR ORGANIC SOLAR CELL APPLICATIONS
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Author
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Grubich, Nicholas
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Date Created
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2014
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Subjects--Topical
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Materials science, Chemistry, Chemistry, Organic
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Description
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Porphyrin light-harvesting systems have recently shown promising solar energy conversion properties in organic photovoltaic devices. Porphyrins, which absorb a broad portion of the solar spectrum and can be easily tuned with peripheral substituent...
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Title
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Synthesis and Reactivity of Benzodiazepine-Derived Heterocyclic Thiones and Selones
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Author
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Clinkscales, Alexander
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Date Created
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2021
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Subjects--Topical
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Chemistry, Inorganic, Chemistry, Organic, Analytical chemistry
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Description
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This thesis outlines the synthesis, characterization and coordination chemistry of new N-heterocylic benzodiazepine thione (NHT) and selone (NHSe) ligands. This new family of ligands, SBzDzArE (Ar = Xy, Mes, Dipp; E = S, Se), contain various bulky...
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Title
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Synthesis and Reactivity of N-Heterocyclic Chalcogenone Complexes of Copper and Silver
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Author
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Allen, Alexander
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Date Created
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2018
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Subjects--Topical
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Chemistry, Inorganic, Chemistry, Organic, Analytical chemistry
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Description
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This presentation outlines the synthesis and characterization of several unusual two-coordinate copper(I) and silver(I) complexes supported by bulky N-heterocyclic thione (NHT) and selone (NHSe) ligands. More specifically, copper(I) complexes of t...
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Title
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Synthesis and Reactivity of Six-Membered N-Heterocyclic Chalcogenones
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Author
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Flanagan, Jerrod
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Date Created
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2017
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Subjects--Topical
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Chemistry, Chemistry, Inorganic
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Description
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The synthesis and coordination chemistry of N-heterocyclic thione (NHT) and selone (NHSe) ligands containing a saturated pyrimidine ring and bulky aromatic substituents on the nitrogen atoms is described in this thesis. To further understand the e...
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Title
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Synthesis, Reactivity, and Applications of Benzimidazole Thiones and Selones
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Author
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Hernandez, Lizeth
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Date Created
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2016
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Subjects--Topical
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Chemistry
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Description
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Benzimidazole-2-thiols and their transition metal complexes have been the focus of intense research due to their potential applications in bioinorganic and organometallic chemistry. Within this field of research, the synthesis and reactivity of be...