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A WATER-SOLUBLE COBALT SULFIDE SUPERATOM FOR FLOW BATTERY APPLICATIONS AND CRYSTALLINE FRAMEWORK SYNTHESIS
Title
A WATER-SOLUBLE COBALT SULFIDE SUPERATOM FOR FLOW BATTERY APPLICATIONS AND CRYSTALLINE FRAMEWORK SYNTHESIS
Author
Freeman, Matthew
Date Created
2019
Subjects--Topical
Chemistry
Description
Metal sulfide clusters are attractive components for flow batteries owing to the abundance of their constituent atoms and their tunable size, solubility, and redox properties. We prepared an atomically precise cobalt sulfide cluster, Co6S8(PTA)6•4...
Bis(bipyridyl)silicon(IV) Diols as Potential Dual Hydrogen Bond Donors for Catalysis
Title
Bis(bipyridyl)silicon(IV) Diols as Potential Dual Hydrogen Bond Donors for Catalysis
Author
Waters, Crystal
Date Created
2016
Subjects--Topical
Chemistry
Description
Hydrogen bond donors (HBDs) have been explored as potential catalysts for the 1,4-conjugate addition and Diels-Alder reactions. HBD catalysis, which relies on Brønsted acid catalytic sites, is being explored as an oxygen and moisture stable altern...
Hexacoordinate Silicon Complexes as Cathodic Colorants
Title
Hexacoordinate Silicon Complexes as Cathodic Colorants
Author
Peloquin, Derek
Date Created
2016
Subjects--Topical
Nanoscience, Chemistry, Chemistry, Inorganic
Description
Electrochemical and spectroelectrochemical characterization of hexacoordinate polypyridine silicon complexes show that they are fitting candidates for electrochromic applications. Tris(bipyridine)silicon(IV), [Si(bpy)3]+4, is colorless in acetonit...
Hypercoordinate Silicon CNC-Pincer Complexes for Electronic Devices
Title
Hypercoordinate Silicon CNC-Pincer Complexes for Electronic Devices
Author
Earnhardt, Adam
Date Created
2022
Subjects--Topical
Chemistry, Chemistry, Organic, Materials science
Description
Previous studies have demonstrated hexacoordinate silicon pincer complexes to be attractive candidates for efficient electron and hole transport layers in organic electronic devices. This work expands the field by incorporating carbon-nitrogen-car...
TRINUCLEAR METAL CHALCOGENIDE CLUSTERS AS PRECURSORS FOR SUPERATOMIC SOLIDS AND CLUSTER ORGANIC FRAMEWORKS
Title
TRINUCLEAR METAL CHALCOGENIDE CLUSTERS AS PRECURSORS FOR SUPERATOMIC SOLIDS AND CLUSTER ORGANIC FRAMEWORKS
Author
Shott, Jessica
Date Created
2017
Subjects--Topical
Nanoscience, Chemistry, Chemistry, Inorganic
Description
Inorganic molecular clusters Ni3(μ3-I)2(μ2-dppm)3 (1), Ni3(μ3-Te)2(μ2-dppm)3 (2), Ni3(μ3-Se)2(μ2-dppm)3 (3), Ni3(μ3-S)2(μ2-dppm)3 (4), Co4(μ3-S)4(PPri3)4 (5), and Mo3(μ3-S)2(μ2-S)3(PMe3)6 (6) have been used as building block precursors in the form...