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Bis(bipyridyl)silicon(IV) Diols as Potential Dual Hydrogen Bond Donors for Catalysis
Title
Bis(bipyridyl)silicon(IV) Diols as Potential Dual Hydrogen Bond Donors for Catalysis
Author
Waters, Crystal
Date Created
2016
Subjects--Topical
Chemistry
Description
Hydrogen bond donors (HBDs) have been explored as potential catalysts for the 1,4-conjugate addition and Diels-Alder reactions. HBD catalysis, which relies on Brønsted acid catalytic sites, is being explored as an oxygen and moisture stable altern...
Hexacoordinate Silicon Complexes as Cathodic Colorants
Title
Hexacoordinate Silicon Complexes as Cathodic Colorants
Author
Peloquin, Derek
Date Created
2016
Subjects--Topical
Nanoscience, Chemistry, Chemistry, Inorganic
Description
Electrochemical and spectroelectrochemical characterization of hexacoordinate polypyridine silicon complexes show that they are fitting candidates for electrochromic applications. Tris(bipyridine)silicon(IV), [Si(bpy)3]+4, is colorless in acetonit...
LIGHT-MATTER INTERACTIONS IN SEMICONDUCTOR NANOWIRES: LIGHT-EFFECT TRANSISTOR AND LIGHT-INDUCED CHANGES IN ELECTRON-PHONON COUPLING AND ELECTRICAL CHARACTERISTICS
Title
LIGHT-MATTER INTERACTIONS IN SEMICONDUCTOR NANOWIRES: LIGHT-EFFECT TRANSISTOR AND LIGHT-INDUCED CHANGES IN ELECTRON-PHONON COUPLING AND ELECTRICAL CHARACTERISTICS
Author
Marmon, Jason
Date Created
2016
Subjects--Topical
Materials science, Electrical engineering, Optics
Description
This dissertation explores three related embodiments of light–matter interactions at the micro– and nano–scales, and is focused towards tangible device applications. The first topic provides a fundamentally different transistor or electronic switc...