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Synthesis and Reactivity of Six-Membered N-Heterocyclic Chalcogenones
Title
Synthesis and Reactivity of Six-Membered N-Heterocyclic Chalcogenones
Author
Flanagan, Jerrod
Date Created
2017
Subjects--Topical
Chemistry, Chemistry, Inorganic
Description
The synthesis and coordination chemistry of N-heterocyclic thione (NHT) and selone (NHSe) ligands containing a saturated pyrimidine ring and bulky aromatic substituents on the nitrogen atoms is described in this thesis. To further understand the e...
TRINUCLEAR METAL CHALCOGENIDE CLUSTERS AS PRECURSORS FOR SUPERATOMIC SOLIDS AND CLUSTER ORGANIC FRAMEWORKS
Title
TRINUCLEAR METAL CHALCOGENIDE CLUSTERS AS PRECURSORS FOR SUPERATOMIC SOLIDS AND CLUSTER ORGANIC FRAMEWORKS
Author
Shott, Jessica
Date Created
2017
Subjects--Topical
Nanoscience, Chemistry, Chemistry, Inorganic
Description
Inorganic molecular clusters Ni3(μ3-I)2(μ2-dppm)3 (1), Ni3(μ3-Te)2(μ2-dppm)3 (2), Ni3(μ3-Se)2(μ2-dppm)3 (3), Ni3(μ3-S)2(μ2-dppm)3 (4), Co4(μ3-S)4(PPri3)4 (5), and Mo3(μ3-S)2(μ2-S)3(PMe3)6 (6) have been used as building block precursors in the form...